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Durham University

Department of Chemistry

Publication details for Dr Mark A. Fox

Patel, N. C. D., Oliva-Enrich, J. M. & Fox, M. A. (2017). Geometries of 11-vertex carborane monoanion radicals with 2n+3 skeletal electron counts. European Journal of Inorganic Chemistry 2017(38-39): 4568-4574.

Author(s) from Durham


While geometries of 12- and 13-vertex dicarbaborane (carborane) radicals with rare 2n+3 skeletal electrons (SEs) have been determined elsewhere, the geometries of the 11-vertex dicarbaborane monoanion radicals with 2n+3 SEs are established here for the first time by computations in agreement with observed electrochemical and electron paramagnetic resonance (EPR) spectroscopy data.