Publication details for Prof. Andrew BeebyGluyas, J.B.G., Manici, V., Gückel, S., Vincent, K.B., Yufit, D.S., Howard, J.A.K., Skelton, B.W., Beeby, A., Kaupp, M. & Low, P.J. (2015). Cross-Conjugated Systems Based On An (E)-Hexa-3-en-1,5-diyne-3,4-diyl Skeleton: Spectroscopic and Spectroelectrochemical Investigations. The Journal of Organic Chemistry 80(22): 11501-11512.
- Publication type: Journal Article
- ISSN/ISBN: 0022-3263 (print), 1520-6904 (electronic)
- DOI: 10.1021/acs.joc.5b02240
- Further publication details on publisher web site
- Durham Research Online (DRO) - may include full text
Author(s) from Durham
A series of cross-conjugated compounds based on an (E)-4,4′-(hexa-3-en-1,5-diyne-3,4-diyl)bis(N,N-bis(4-methoxyphenyl)aniline) skeleton (1–6) have been synthesized. The linear optical absorption properties can be tuned by modification of the substituents at the 1 and 5 positions of the hexa-3-en-1,5-diynyl backbone (1: Si(CH(CH3)2)3, 2: C6H4C≡CSi(CH3)3, 3: C6H4COOCH3, 4: C6H4CF3, 5: C6H4C≡N, 6: C6H4C≡CC5H4N), although attempts to introduce electron-donating (C6H4CH3, C6H4OCH3, C6H4Si(CH3)3) substituents at these positions were hampered by the ensuing decreased stability of the compounds. Spectroelectrochemical investigations of selected examples, supported by DFT-based computational studies, have shown that one- and two-electron oxidation of the 1,2-bis(triarylamine)ethene fragment also results in electronic changes to the perpendicular π-system in the hexa-3-en-1,5-diynyl branch of the molecule. These properties suggest that (E)-hexa-3-en-1,5-diynyl-based compounds could have applications in molecular sensing and molecular electronics.