Publication details for Dr Dominikus HeiftHeift, D., Benkő, Z. & Grützmacher, H. (2014). Coulomb repulsion versus cycloaddition: formation of anionic four-membered rings from sodium phosphaethynolate, Na(OCP). Dalton Transactions 43(2): 831-840.
- Publication type: Journal Article
- ISSN/ISBN: 1477-9226 (print), 1477-9234 (electronic)
- DOI: 10.1039/C3DT52359D
- Further publication details on publisher web site
Author(s) from Durham
Carbon dioxide and two equivalents of Na(OCP) form, in an equilibrium reaction, a CO2 adduct of the composition Na2(P2C3O4). The anion of this salt, [O2C–P(CO)2P]2−, is built up by a four-membered 1,3-diphosphetane-2,4-dione ring and a carboxylate unit attached to one of the phosphorus atoms. A remarkable π-delocalization was observed within the OCPCO moiety. The stepwise reaction mechanism leading to Na2(P2C3O4) was investigated with quantum chemical calculations. Accompanied by the release of CO2, Na2(P2C3O4) reacts with both 2-iodopropane and 4,4′,4′′-trimethoxytriphenylmethyl chloride to form four-membered cyclic anions. For comparison the analogous reactions were performed with Na(OCP) instead of Na2(P2C3O4) and the results are discussed in detail.