Publication details for Dr Chris GrovesMendis, Budhika G. , Bishop, Sarah J. , Groves, Chris , Szablewski, Marek , Berlie, Adam & Halliday, Douglas P. (2013). Plasmon-loss imaging of polymer-methanofullerene bulk heterojunction solar cells. Applied Physics Letters 102(25): 253301.
- Publication type: Journal Article
- ISSN/ISBN: 0003-6951 (print), 1077-3118 (online)
- DOI: 10.1063/1.4812485
- Further publication details on publisher web site
- Durham Research Online (DRO) - may include full text
Author(s) from Durham
The plasmon feature in an electron energy loss spectrum provides unique insight into poly(3-hexylthiophene) (P3HT)-phenyl-C61-butyric acid methyl ester (PCBM) solar cells. Analysis of the intensity, shape, and energy of the plasmon reveals information about the type of phase, distribution of P3HT semi-crystalline fibres, and PCBM packing density at high spatial resolution. Plasmon-loss imaging has also revealed nano-scale residual solvent pockets with preferentially dissolved PCBM. A robust tomography method for reconstructing the 3D morphology of the bulk heterojunction thin-film via plasmon-loss images is also presented. The analysis techniques can be used to investigate morphology evolution during thin-film processing and its effect on device performance.