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Durham University

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Publication details for Professor Andy Monkman

GOLDENBERG, LM, COOKE, G, PEARSON, C, MONKMAN, AP, BRYCE, MR & PETTY, MC (1994). ELECTROCHEMICAL PROPERTIES OF HEXADECANOYLTETRATHIAFULVALENE LANGMUIR-BLODGETT-FILMS. Thin Solid Films 238(2): 280-284.
  • Publication type: Journal Article
  • ISSN/ISBN: 0040-6090
  • Keywords: CHEMICALLY MODIFIED ELECTRODES

Author(s) from Durham

Abstract

The electrochemical behaviour of monolayer and multilayer films of
hexadecanoyltetrathiafulvalene, deposited on conductive substrates by
the Langmuir-Blodgett technique, has been studied by cyclic
voltammetry, chronoamperometry and visible/infrared spectroscopy.
Monolayer films show stable reversible oxidation to the cation-radical
state. However, in thicker structures, the electrochemical response is
strongly distorted because of the hindered diffusion of ions.