Publication details for Prof. David J. TozerGooseman, N.E.J., O'Hagan, D., Slawin, A.M.Z., Teale, A.M., Tozer, D.J. & Young, R.J. (2006). The intramolecular β-fluorine⋯ammonium interaction in 4- and 8-membered rings. Chemical Communications (30): 3190-3192.
- Publication type: Journal Article
- ISSN/ISBN: 1359-7345, 1364-548X
- DOI: 10.1039/b606334a
- Further publication details on publisher web site
Author(s) from Durham
The structures of 3-fluoroazetidinium hydrochloride and 3-fluoro-1,5-diazacyclooctane hydrobromide are explored both by X-ray diffraction analysis and DFT calculations, and the conformations of these molecules are shown to be significantly influenced by the through space C–F⋯N+ interaction.