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Durham University

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Publication details for Prof. David J. Tozer

Gooseman, N.E.J., O'Hagan, D., Slawin, A.M.Z., Teale, A.M., Tozer, D.J. & Young, R.J. (2006). The intramolecular β-fluorine⋯ammonium interaction in 4- and 8-membered rings. Chemical Communications (30): 3190-3192.

Author(s) from Durham


The structures of 3-fluoroazetidinium hydrochloride and 3-fluoro-1,5-diazacyclooctane hydrobromide are explored both by X-ray diffraction analysis and DFT calculations, and the conformations of these molecules are shown to be significantly influenced by the through space C–F⋯N+ interaction.