Department of Chemistry
Dr. J. A. Gareth Williams
Publications
(133) L. Murphy, P. Brulatti, V. Fattori, M.
Cocchi and J.A.G. Williams, Blue-shifting the monomer and
excimer phosphorescence of tridentate cyclometallated platinum(II)
complexes for optimal white-light OLEDs, Chem. Commun. 2012, 48, 5817-5819.
(132) R. Muñoz-Rodriguez, E.
Buñuel, J. A. G. Williams and D. J. Cárdenas,
Divergent luminescence behaviour from differential interactions in
dinuclear Pt, Au, and mixed Pt-Au complexes built on a xanthene
scaffold, Chem. Commun. 2012,
in press.
(131) L. Ordronneau, H. Nitadori, I.
Ledoux, A. Singh, J. A. G. Williams, M. Akita, V. Guerchais and H. Le
Bozec, Photochromic metal complexes: photoregulation of both the
nonlinear optical and luminescence properties, Inorg. Chem. 2012, 51, 5627-5636.
(130) E. Baggaley, J.A. Weinstein
and J.A.G.
Williams, Lighting the way to see inside the cell with
luminescent transition metal complexes, Coord. Chem. Rev. 2012, in press.
(129) P. Brulatti, R. J. Gildea, J. A. K.
Howard, V. Fattori, M. Cocchi and J.
A. G. Williams, Luminescent iridium(III) complexes with
N^C^N-coordinated ligands: dual tuning of the emission energy and
application to organic light-emitting devices (OLEDs), Inorg. Chem. 2012, 51,
3813-3826.
(128) E. Rossi, A. Colombo, C.
Dragonetti, D. Roberto, R. Ugo, A.
Valore, L. Falciola, P. Brulatti, M. Cocchi and J.A.G. Williams,
Novel N^C^N–cyclometallated platinum complexes with acetylide
coligands
as efficient phosphors for OLEDs, J.
Mater. Chem. 2012, 22,
10650-10655.
(127)
G.R. Freeman and J.A.G.
Williams, Metal complexes of pincer ligands: excited
states, photochemistry, and luminescence, Top. Organomet. Chem., 2012, in press.
(126) K. Beydoun, M. Zaarour,
J.A.G. Williams, H. Doucet and V. Guerchais, Palladium-catalysed
direct arylation of a tris-cyclometallated Ir(III) complex bearing
2,2'-thienylpyridine ligands: A powerful tool for the tuning of
luminescence properties, Chem.
Commun., 2012, 48, 1260-1262.
(125)
A. Rausch, L. Murphy, J.A.G.
Williams, H. Yersin, Improving the performance of Pt(II)
complexes for blue light emission by enhancing the molecular rigidity, Inorg. Chem. 2012, 51, 312-319.
(124) A.M. Prokhorov, A.
Santoro, J.A.G. Williams and D.W. Bruce, Phosphorescent
mesomorphic dyads based on tetraacetylethane complexes of
iridium(III), Angew. Chem. Int. Ed.
2012, 51, 95-98.
(123)
E. Rossi, L. Murphy, P.L. Brothwood,
A. Colombo, C. Dragonetti, D. Roberto, R. Ugo, M. Cocchi and J.A.G.
Williams, Cyclometallated platinum(II) complexes of
1,3-di(2-pyridyl)benzenes: tuning excimer emission from red to
near-infrared for NIR-OLEDs, J.
Mater. Chem. 2011, 21,
15501-15510.
(122)
E. Anger, M. Rudolph, L. Norel, S.
Zrig, C. Shen, N. Vanthuyne, L. Toupet, J. A. G. Williams, C. Roussel,
J. Autschbach, J. Crassous and R. Réau, Multifunctional
and reactive enantiopure organometallic helicenes: Tuning chiroptical
properties by structural variations of mono- and
bis-(platinahelicene)s, Chem. Eur.
J. 2011, 17, 14178-14198.
(121)
V.N. Kozhevnikov, M.C. Durrant and
J.A.G. Williams, Highly luminescent mixed-metal Pt(II)/Ir(III)
complexes: bis-cyclometalation of 4,6-diphenylpyrimidine as a versatile
route to rigid multimetallic assesmblies, Inorg. Chem. 2011, 50, 6304-6313.
(120) C. Latouche, P.-H.
Lanoë, J.A.G. Williams, V. Guerchais, A. Boucekkine and J.-L.
Fillaut, Switching of excited states in cyclometalated
platinum complexes incorporating pyridyl-acetylide ligands (Pt-C≡C-py):
a combined experimental and theoretical study, New J. Chem. 2011, 35, 2196-2202.
(119)
W. Mróz, C. Botta, U.
Giovanella, E. Rossi, A. Colombo, C.
Dragonetti, D. Roberto, R. Ugo, A. Valore and J.A.G. Williams,
Cyclometallated platinum(II) complexes of 1,3-di(2-pyridyl)benzenes for
solution-processable WOLEDs exploiting monomer and excimer
phosphorescence, J. Mater. Chem.
2011, 21, 8653-8661.
(118) V. Aubert, L. Ordronneau,
M. Escadeillas, J.A.G. Williams, A. Boucekkine, E. Coulaud, C.
Dragonetti, S. Righetto, D. Roberto, R. Ugo, A. Valore, A. Singh, I.
Ledoux, H. Le Bozec and V. Guerchais, Linear and nonlinear
optical properties of cationic bipyridyl iridium(III) complexes:
tunable and photoswitchable? Inorg.
Chem. 2011, 50, 5027-5038.
(117) D.N. Kozhevnikov, V.N. Kozhevnikov,
M.Z. Shafikov, A.M. Prokhorov, D.W. Bruce and J.A.G. Williams,
Phosphorescence versus fluorescence in cyclometallated platinum(II) and iridium(III) complexes of
(oligo)thienylpyridines, Inorg. Chem.
2011, 50, 3804-3815.
(116)
J.
Kalinowski, V. Fattori, M. Cocchi and
J.A.G. Williams, Light-emitting devices based on organometallic
platinum complexes as emitters, Coord.
Chem. Rev. 2011, 255, 2401-2425.
(115) A. Santoro, A.M.
Prokhorov, V.N. Kozhevnikov, A.C. Whitwood, B. Donnio, J.A.G. Williams
and D.W. Bruce, Emissive metallomesogens based on
2-phenylpyridine complexes of iridium(III), J. Am. Chem. Soc. 2011, 133,
5248-5251.
(114) P.-H. Lanoe, J.-L.
Fillaut, V. Guerchais,
H. Le Bozec and J.A.G. Williams, Metal cation-induced modulation
of the photophysical properties of a platinum(II) complex featuring a
dipicolylanilino-acetylide ligand, Eur.
J. Inorg. Chem. 2011, 1255-1259.
(113) S. Druet, C.O.
Paul-Roth, V. Fattori, M.
Cocchi and J.A.G. Williams, Platinum and palladium complexes of
fluorenyl porphyrins as red phosphors for light-emitting devices, New J. Chem. 2011, 35, 438-444.
(112) L. Murphy, A. Congreve,
L.-O. Palsson and
J.A.G. Williams, The time domain in co-stained cell imaging:
time resolved emission imaging microscopy using a protonatable
luminescent iridium complex, Chem.
Commun. 2010, 46,
8743-8745.
(111) J.
Kalinowski, M. Cocchi, L. Murphy, J.A.G. Williams and V. Fattori, Bimolecular emissive excited states in Pt(II)
complexes for high-performance organic light emitting diodes, Chem. Phys. 2010, 378, 47-57.
(110) J.
Kalinowski, M. Cocchi, V. Fattori, L. Murphy and J.A.G. Williams,
Unified approach to electroluminescence efficiency in organic
light-emitting diodes, Organic
Electronics, 2010, 11, 724-730.
(109) S. Graule, M. Rudolph, W.
Shen, J.A.G. Williams, C. Lescop, J. Autschbach, J. Crassous and R.
Réau, Assembly of pi-conjugated phosphole-azahelicene
derivatives into chiral coordination complexes: a combined experimental
and theoretical study, Chem.
Eur. J. 2010, 16,
5976-6005.
(108)
K.L. Garner, L.F. Parkes, J.D. Piper
and J.A.G. Williams, Luminescent platinum complexes with
terdentate ligands forming 6-membered chelate rings: advantageous and
deleterious effects in N^N^N and N^C^N-coordinated complexes, Inorg. Chem. 2010, 49, 476-487.
(107) M. Cocchi, J.
Kalinowski, L. Murphy, J.A.G. Williams, and V. Fattori, Mixing
of molecular exciton and excimer phosphorescence to tune colour and
efficiency of organic LEDs, Organic
Electronics, 2010, 11,
388-396.
(106) J.C. Araya, J. Gajardo, S.A. Moya, P.
Aguirre, L. Toupet, J.A.G. Williams, M. Escadeillas, H. Le Bozec and V.
Guerchais, Modulating the luminescence of an iridium(III)
complex incorporating a di(2-picolyl)anilino-appended bipyridine ligand
by Zn2+ cations, New J.
Chem., 2010, 34, 21-24.
(105) L. Murphy and J.A.G.
Williams, Luminescent platinum compounds: from molecules to OLEDs,
Topics in Organometallic Chemistry, 2010, 28,
75-111 (edition on
organotransition metal complexes
for optics).
(104) L. Norel, M. Rudolph, N.
Vanthuyne, J.A.G. Williams, C. Lescop, C. Roussel, J. Autschbach, J.
Crassous and R. Réau, Metallahelicenes: a novel family
of easily accessible helicene derivatives exhibiting large and tuneable
chiroptical properties, Angew. Chem.
Int. Ed. 2010, 49,
99-102.
(103) P.-H. Lanoë, H. Le Bozec,
J.A.G. Williams, J.-L. Fillaut and V. Guerchais, Cyclometallated
platinum(II) complexes containing pyridyl-acetylide ligands: the
selective influence of lead binding on luminescence, Dalton Trans. 2010, 39, 707-710.
(102) A. Rausch, L. Murphy,
J.A.G. Williams and H.
Yersin, Probing the excited state properties of the highly
phosphorescent Pt(dpyb)Cl compound by high-resolution optical
spectroscopy, Inorg. Chem., 2009,
28, 11407-11414.
(101)
P. Wiggins, J.A.G. Williams and D.J. Tozer, Excited state
surfaces in density functional theory: A new twist on an old problem, J. Chem. Phys. 2009, 131, 091101.
(100) J.A.G.
Williams, The
coordination chemistry of dipyridylbenzene: N-deficient terpyridine or
panacea for brightly luminescent metal complexes?, Chem. Soc. Rev., 2009,
38, 1783-1801.
(99) A. Santoro, A.
C. Whitwood, J.A.G.
Williams, V. Kozhevnikov, and D. W. Bruce,
Synthesis, mesomorphism and
luminescent properties of calamitic 2-phenylpyridines and their
complexes with platinum(II), Chem.
Mater. 2009, 21,
3871-3882.
(98) C. She, J.E.
McGarrah, S.J.
Lee, J.L. Goodman, S.T. Nguyen, J.A.G. Williams, and J.T. Hupp, Probing
exciton localization / delocalization: transient DC photoconductivity
studies of excited states of symmetrical porphyrin monomers, oligomers
and supramolecular assemblies, J. Phys. Chem. A, 2009, 113, 8182-8186.
(97) V.L. Whittle and J.A.G.
Williams, Cyclometallated bis-terdentate iridium complexes as
linearly expandable cores for the construction of multimetallic
assemblies, Dalton Trans. 2009, 3929-3940 (invited
contribution to theme edition on Supramolecular Photochemistry).
(96) John Haycock, Stanley Botchway, Julia
Weinstein and Gareth Williams, Long-life fluorescent imaging of
cells in real time, SPIE Newsroom,
2009, DOI: 10.1117/2.1200906.1684.
(95) M. Cocchi, J. Kalinowski, V. Fattori, J.A.G. Williams and L.
Murphy, Colour-variable highly efficient organic
electrophosphorescent diodes manipulating molecular exciton and excimer
emissions, Appl. Phys. Lett.,
2009, 94, 073309.
(94) V. Aubert, E. Ishow, F.
Ibersienne, A. Boucekkine, J.A.G.
Williams, L. Toupet, R. Métivier, K. Nakatani, V. Guerchais and H. Le
Bozec, A "reverse interruptor": the novel
molecular design of a
fluorescent photochromic DTE-based bipyridine, New J. Chem., 2009,
33, 1320-1323 (theme
edition on photochromic molecules).
(93) D.L. Rochester, S. Develay,
S. Zalis and J.A.G. Williams, Localised to
intraligand charge-transfer excited states in cyclometalated platinum
complexes: an experimental and theoretical study into the influence of
electron-rich pendants and modulation of excited states by ion
binding, Dalton Trans. 2009, 1728-1741.
(92) V. Fattori,
J.A.G. Williams, L. Murphy, M. Cocchi, J.
Kalinowski, Organic light sources look forward to optimize the
photosynthesis process, Photonics and Nanostructures - Fundamentals
and Applications, 2008, 6,
225-230.
(91) S. Develay, O.
Blackburn, A.L. Thompson and J.A.G. Williams,
Cyclometalated platinum(II) complexes of pyrazole-based,
N^C^N-coordinating, terdentate ligands: the contrasting influence of
pyrazolyl and pyridyl rings on luminescence, Inorg. Chem. 2008,
47, 11129-11142.
(90) S.W. Botchway, M. Charnley,
J.W. Haycock, A.W. Parker, D.L. Rochester, J.A. Weinstein and J.A.G.
Williams, Time-resolved and two-photon emission imaging microscopy
of live cells with inert platinum complexes, Proc. Natl. Acad. Sci.
USA, 2008, 105, 16071-16076.
(89) A. D'Aléo, A. Picot,
A. Beeby, J.A.G. Williams, B. Le Guennic, C. Andraud, O. Maury, Efficient
sensitization of europium, ytterbium and neodymium functionalized
tris-dipicolinate lanthanide complexes through tunable charge-transfer
excited states, Inorg. Chem., 2008, 47, 10258-10268.
(88) P.-H. Lanoë, J.-L.
Fillaut, L. Toupet, J. A.G. Williams, H. Le Bozec and V. Guerchais,
Cyclometallated platinum(II) complexes incoporating ethynyl-flavone
ligands: switching between triplet and singlet emission induced by
selective binding of Pb(II) ions, Chem. Commun., 2008, 4333-4335.
(87) S. Develay and J.A.G. Williams, Intramolecular excimers
based on rigidly-linked platinum(II) complexes: intense deep-red
triplet luminescence in solution, Dalton Trans. 2008, 4562-4564.
(86) J.A.G. Williams, S. Develay,
D.L. Rochester and L. Murphy, Optimising the luminescence of
platinum(II) complexes and their application in organic light emitting
devices (OLEDs), Coord. Chem. Rev. 2008, 252, 2596-2611, invited
contribution to ISPPCC-17 edition.
(85) V.L. Whittle and
J.A.G.
Williams, A new class of iridium complexes suitable for stepwise
incorporation into linear assemblies: synthesis, electrochemistry, and
luminescence, Inorganic Chemistry, 2008, 47, 6596-6607. (Featured
on the front cover of the journal issue).
(84) M. Cocchi, J. Kalinowski, D. Virgili and J.A.G. Williams,
Excimer-based red / near-infrared organic light-emitting diodes with
very high quantum efficiency, Appl. Phys. Lett. 2008, 92, 113302.
(83) J.A.G. Williams, A.J.
Wilkinson and V.L. Whittle, Perspective article: Light-emitting
iridium complexes with tridentate ligands, Dalton Trans. 2008,
2081-2099.
(82) J.-L. Fillaut, J. Andriés, R.D. Marwaha, P.-H.
Lanoë, O. Lohio, L. Toupet, and J.A.G. Williams, Flavonol
based ruthenium acetylides as fluorescent chemosensors for lead ions, J. Organomet. Chem., 2008, 693, 228-234.
(81) J. Kalinowski,
M. Cocchi, D. Virgili, V. Fattori and J.A.G.
Williams, Mixing of excimer and exciplex emission: a new way to
improve white light emitting organic electrophosphorescent diodes,
Advanced Materials, 2007,
19, 4000-4005.
(80) A.J. Wilkinson,
D. Maffeo,
A. Beeby, C.E. Foster and J.A.G. Williams, Sensitization of
europium(III) luminescence by benzophenone-containing ligands:
Regioisomers, rearrangements and chelate ring size, and their influence
on quantum yields, Inorganic Chemistry, 2007, 46, 9438-9449.
(79) J. Kalinowski,
M. Cocchi, D. Virgili, V. Fattori and J.A.G.
Williams, Electro-photoluminescence in organics, Chem. Phys.
Lett., 2007, 447, 279-283.
(78) J.A.G.Williams, "The
Photochemistry and photophysics of coordination complexes – Platinum",
eds. V. Balzani and S. Campagna, Topics in Current Chemistry,
2007, 281, 205-268.
(77) C.O. Paul-Roth, J.A.G.
Williams, J. Letessier and G. Simonneaux, New tetra-aryl and
biaryl porphyrins bearing 5,15-related fluorenyl pendants: The
influence of arylation on fluorescence, Tetrahedron Lett. 2007, 48,
4317-4322.
(76) M. Cocchi, J. Kalinowski, D.
Virgili, V. Fattori, S. Develay and J.A.G. Williams, Single-dopant
organic white electrophosphorescent diodes with very high efficiency
and its reduced current density roll-off, Appl. Phys. Lett., 2007, 90,163508.
(75) J. Kruusma, A.
Rhodes, R.
Bhatia, J.A.G. Williams, A. Benham and R. Kataky, The effect of
a hydrogen bonding environment (dimethyl sulfoxide) on the ionisation
and redox properties of
the thiol group in cysteine and a protein disulfide isomerase mimic
(vectrase),
J. Solution Chem., 2007, 36,
517-529.
(74) A. Picot, F.
Malvolti, B. Le
Guennic, P.L. Baldeck, J.A.G. Williams, C. Andraud and O.Maury, Two
photon antenna effect induced in octupolar europium complexes,
Inorg. Chem., 2007, 46,
2659-2665.
(73) M. Cocchi, D.
Virgili, V.
Fattori, D.L. Rochester and J.A.G. Williams, N^C^N-Coordinated
platinum(II) complexes as phosphorescent emitters in high-performance
organic light-emitting devices, Adv. Funct. Mater., 2007, 17, 285-289.
(72) A.
Barbieri, F.
Barigelletti, C. Sabatini, K.J. Arm and
J.A.G. Williams, Fast, through-bond mediated energy transfer from
Ir(III) to Ru(II) in di- and tetranuclear heterometallic assemblies:
elucidation of a two-step Ir → Ir → Ru energy transfer process,
Photochem. Photobiol. Sci., 2007, 6,
397-405 (special issue celebrating
the 70th birthday of Vincenzo Balzani).
(71) M.
Cocchi, D. Virgili, V.
Fattori, J.A.G. Williams and J. Kalinowski, Highly efficient
near-infrared organic excimer electrophosphorescent diodes, Appl.
Phys. Lett., 2007, 90, 023506.
(70) J. Kruusma, A.M. Benham, J.A.G. Williams and R. Kataky, A
brief overview about the proteins and the processes responsible for the
formation of the native-folded thioproteins in the pro- and eukaryotic
cells, Portugaliae Electrochim. Acta 2006, 24, 207-228.
(69) D. Virgili,
M.Cocchi, V.
Fattori, C. Sabatini, J. Kalinowski and J.A.G. Williams, Highly
efficient exciplex phosphorescence from organic light-emitting diodes, Chem.
Phys. Lett., 2006, 433,
145-149.
(68) J. Kalinowski,
M. Cocchi, D.
Virgili, V. Fattori and J.A.G.Williams, Evidence for electric
field dependent dissociation of exciplexes in electron donor–acceptor
organic solid films, Chem. Phys.
Lett., 2006, 432, 110-115.
(67) A.J. Wilkinson,
H.
Puschmann, J.A.K. Howard, C.E. Foster and J.A.G. Williams,
Luminescent complexes of iridium(III) containing N^C^N-coordinating
terdentate ligands, Inorg. Chem., 2006, 45, 8685-8699.
(66) B. Yin, F. Niemeyer, J.A.G. Williams, J.
Jiang, A.
Boucekkine, L. Toupet, H. Le Bozec and V. Guerchais, Synthesis,
structures and photophysical properties of luminescent platinum(II)
complexes containing cyclometallated 4-styryl-functionalized
2-phenylpyridine ligands, Inorg. Chem., 2006, 45, 8584-8596.
(65) K.
Sénéchal-David, A. Hemeryck, N. Tancrez, L.
Toupet, J.A.G. Williams, I. Ledoux, J. Zyss, A. Boucekkine, J.-P.
Guégan, H. Le Bozec and O. Maury, Synthesis, structural
studies, theoretical calculations, linear and nonlinear optical
properties of terpyridyl lanthanide complexes: new evidence for the
contribution of f electrons to the NLO activity, J. Am. Chem. Soc.,
2006, 128, 12243-12255.
(64) S. Dias-Gunasekara, M. van Lith, J.A.G. Williams, R. Kataky
and A.M. Benham, The FAD binding domain prevents stress-induced
misfolding of the endoplasmic reticulum oxidoreductase Ero1β, J.
Biol. Chem., 2006, 281,
25018-25025.
(63) K.J. Arm and
J.A.G.
Williams, A cross-coupling strategy for the synthesis of
dimetallic assemblies containing mixed bipyridine-terpyridine bridging
ligands: luminescence and energy transfer properties, Dalton Trans., 2006, 2172-2174.
(62) R.C. Evans, P.
Douglas, J.A.G. Williams and D.L. Rochester, A
novel luminescence-based colorimetric oxygen sensor with a "traffic
light" response, J. Fluorescence, 2006, 16, 201-206 (special issue on
Methods and Applications in Fluorescence Spectroscopy).
(61) J. Kruusma, A.M.
Benham,
J.A.G. Williams and R. Kataky, An introduction to thiol redox
proteins in the endoplasmic reticulum and a review of current
electrochemical methods of detection of thiols, Analyst, 2006, 131, 459-473.
(60) K.J. Arm, W. Leslie and J.A.G. Williams, Synthesis and
pH-sensitive luminescence of bis-terpyridyl iridium(III) complexes
incorporating pendent pyridyl groups, Inorg. Chim. Acta, 2006, 359, 1222-1232. Also featured
in Platinum Metals Review, April 2006.
(59) S.J. Farley, D.L. Rochester,
A.L. Thompson, J.A.K. Howard and J.A.G. Williams, Controlling
emission energy, self-quenching and excimer formation in highly
luminescent N^C^N-coordinated platinum(II) complexes, Inorg. Chem.,
2005, 44, 9690-9703.
(58) S. Dias-Gunasekara, J.
Gubbens, M. van Lith, C. Dunne, J.A.G. Williams, R. Kataky, D. Scoones,
A. Lapthorn, N. Bulleid and A.M. Benham, Tissue specific
expression and dimerisation of the endoplasmic reticulum oxidoreductase
Ero1-beta, J. Biol. Chem.,
2005, 280, 33066-33075.
(57) A.J.S. Bexon and J.A.G.
Williams, Luminescent complexes of iridium(III) with
6'-phenyl-2,2'-bipyridine and 4'-aryl derivatives: N^C versus N^N
coordination, Comptes Rendus Chimie, 2005, 8, 1326-1335 (special issue on
Molecular Materials).
(56) A.M. Costero, J. Sanchis, S. Gil, V. Sanz and J.A.G.
Williams, Polyamine biphenyl derivatives as fluorescent sensors
for anions and cations, J. Mater. Chem., 2005, 15, 2848-2853 (special
issue
on Fluorescent Sensors).
(55) K.J. Arm and J.A.G. Williams,
Boronic acid-substituted metal complexes: versatile building blocks for
the synthesis of multimetallic assemblies, Chem. Commun., 2005,
230-232.
"Hot Paper" - available free of charge at http://xlink.rsc.org/?DOI=b414929g
(54) A.J. Wilkinson, A.E.
Goeta,
C.E. Foster and J.A.G. Williams,
Synthesis and luminescence of a charge-neutral
cyclometalated iridium(III) complex containing N^C^N- and
C^N^C-coordinating
terdentate ligands, Inorg. Chem., 2004, 43, 6513-6515.
(53) W. Leslie, R.A. Poole,
P.R.
Murray, L.J. Yellowlees, A. Beeby and J.A.G. Williams, Near
infra-red
luminescence from bis-terpyridyl iridium(III) complexes incorporating
electron-rich
pendants, Polyhedron, 2004, 23, 2769-2777.
(52) A.M. Costero, J.
Sanchis,
S. Gil, V. Sanz, M.C. RamÌrez de Arellano and J.A.G. Williams, Polyazapodands
derived from biphenyl. Study of their behaviour as conformationally
regulated
fluorescent sensors, Supramol. Chem., 2004, 16, 435-446.
(51) A.M. Costero, S.
Gil,
J. Sanchis, S. Peransí, V. Sanz and J.A.G. Williams, Conformationally
regulated fluorescent sensors. Study of the selectivity in Zn2+
versus Cd2+ sensing, Tetrahedron, 2004,
60, 6327-6334.
(50) W. Leslie, A.S. Batsanov,
J.A.K. Howard and J.A.G. Williams,
Cross-couplings in the elaboration
of luminescent bis-terpyridyl iridium complexes: the effect of extended
or inhibited conjugation on emission, J. Chem. Soc., Dalton Trans.,
2004, 623-631.
(49) J.A.G. Williams, A.
Beeby,
E.S. Davies, J.A. Weinstein and C. Wilson, An alternative route to
highly luminescent platinum(II) complexes: cyclometalation with
N^C^N-coordinating
dipyridylbenzene ligands, Inorg. Chem., 2003, 42, 8609-8611.
(48) D. Maffeo and J.A.G.
Williams,
Intramolecular
sensitisation of europium(III) luminescence by 8-benzyloxyquinoline in
aqueous solution, Inorg. Chim. Acta, 2003, 355, 133-142.
(47) D. Parker and J.A.G.
Williams,
"Responsive luminescent lanthanide complexes", in "Metal Ions in
Biological
Systems, Volume 40: The lanthanides and their interactions with
biosystems",
ed. A. Sigel and H. Sigel, Marcel Dekker, New York, 2003.
(46) B.G. Davis, D.P.G.
Emmerson
and J.A.G. Williams, "Oxidation and Reduction" in "Organic Reaction
Mechanisms 1998", ed. A.C. Knipe and W.E. Watts, John Wiley:
Chichester,
2003, chapter 5, pages 217-252.
(45) W. Goodall, K. Wild, K.J.
Arm and J.A.G. Williams, The synthesis of 4'-aryl substituted
terpyridines
by Suzuki cross-coupling reactions: substituent effects on ligand
fluorescence,
J. Chem. Soc., Perkin Trans. 2, 2002, 1669-1681.
(44) A. Beeby, S. Faulkner and
J.A.G. Williams, pH-Dependence of the energy transfer mechanism in
a phenanthridine-appended ytterbium complex,
J. Chem. Soc., Dalton Trans.,
2002, 1918-1922.
(43) A. Beeby, L.M. Bushby, D.
Maffeo and J.A.G. Williams, Intramolecular sensitisation of
lanthanide(III)
luminescence by acetophenone-containing ligands: the critical effect of
para-substituents and solvent, J. Chem. Soc., Dalton Trans., 2002,
48-54.
(42) W. Goodall and J.A.G.
Williams,
A new, highly fluorescent terpyridine which responds to zinc ions with
a large red-shift in emission,
Chem. Commun., 2001, 2514-2515.
(41) C.J. Aspley and J.A.G.
Williams,
Palladium-catalysed cross-coupling reactions of ruthenium
bis(terpyridyl)
complexes: strategies for the incorporation and exploitation of boronic
acid functionality, New J. Chem., 2001,
25, 1136-1147.
(40) A. S. Batsanov, A.E.
Goeta,
J.A.K. Howard, D. Maffeo, H. Puschmann and J.A.G. Williams,
Nickel(II)
complexes of the isomeric tetraazamacrocyclic ligands 1,11- and 1,8-
bis(2-pyridylmethyl)-cyclam
and of a structurally constrained N(4), N(8)-methylene bridged
analogue,
Polyhedron,
2001, 20, 981-986.
(39) B.G. Davis and J.A.G.
Williams,
"Oxidation
and Reduction" in "Organic Reaction Mechanisms 1997", ed. A.C. Knipe
and
W.E. Watts, John Wiley: Chichester, 2001, chapter 5, pages 179 - 219.
(38) R.L. Luck, C.L. Maupin,
D.
Parker, J.P. Riehl and J.A.G. Williams,
Circularly polarised luminescence
and structural studies of a dysprosium(III) complex with an octadentate
macrocyclic ligand bearing benzylphosphinate groups, Inorg. Chim.
Acta,
2001, 317, 331-337.
(37) A. Beeby, S. Faulkner, D.
Parker and J.A.G. Williams, Sensitised luminescence from
phenanthridine
appended lanthanide complexes: analysis of triplet mediated energy
transfer
processes in terbium, europium and neodymium complexes, J. Chem.
Soc.,
Perkin Trans. 2, 2001, 1268-1273.
(36) G. Bobba, R.S. Dickins,
S.D.
Kean, C.E. Mathieu, D. Parker, R.D. Peacock, G. Siligardi, M.J. Smith,
J.A.G. Williams and C.F.G.C. Geraldes,
Chiroptical, ESMS and NMR spectroscopic
study of the interaction of enantiopure lanthanide complexes with
selected
self-complementary dodecamer oligonucleotides,
J. Chem. Soc., Perkin
Trans. 2, 2001, 1729-1737.
(35) A.E. Goeta, J.A.K.
Howard,
D Maffeo, H. Puschmann, J.A.G. Williams and D.S. Yufit, Copper(II)
complexes of the isomeric tetraazamacrocyclic ligands 1,11- and
1,8-bis(2-pyridylmethyl)-1,4,8,11-tetraazacyclotetradecane
and of the 1,4,8,11-tetraazacyclotetradecane-5,12-dione analogue at
neutral
and basic pH, J. Chem. Soc., Dalton Trans., 2000, 1873-1880.
(34) A. Beeby, L.M. Bushby, D.
Maffeo and J.A.G. Williams,
The efficient intramolecular sensitisation
of terbium(III) and europium(III) by benzophenone containing ligands, J.
Chem. Soc., Perkin Trans. 2, 2000, 1281-1283.
(33) W. Goodall and J.A.G.
Williams,
Iridium(III) bis-terpyridine complexes incorporating pendent
N-methylpyridinium
groups: luminescent sensors for chloride ions, J. Chem. Soc.,
Dalton
Trans., 2000, 2893-2895.
(32) A. Beeby, R.S. Dickins, S.
Fitzgerald,
L.J. Govenlock, C.L. Maupin, D. Parker, J.P. Riehl, G. Siligardi and
J.A.G.
Williams, Porphyrin sensitisation of circularly polarised near-IR
lanthanide
luminescence: enhanced emission with nucleic acid binding, Chem.
Commun.,
2000, 1183-1184.
(31) C.L. Maupin, R.S.
Dickins,
L.G. Govenlock, C.E. Mathieu, D. Parker, J.A.G. Williams and J.P.
Riehl,
The
measurement of circular polarization in the near-IR luminescence from
chiral
complexes of Yb(III) and Nd(III),
J. Phys. Chem. A, 2000,
104,
6709-6717.
(30) A. Beeby, S.W. Botchway,
I.M. Clarkson, S Faulkner, A.W. Parker, D. Parker and J.A.G. Williams,
Luminescence
imaging microscopy and lifetime mapping using kinetically stable
lanthanide(III)
complexes,
J. Photochem. Photobiol. B, 2000,
57, 83-89.
(29) M. Licini and J.A.G.
Williams,
Iridium(III) bis-terpyridine complexes displaying long-lived pH
sensitive
luminescence, Chem. Commun., 1999, 1943-1944.
(28) L. Flamigni, F.
Barigelletti,
N. Armaroli, B. Ventura, J.-P. Collin, J.-P. Sauvage and J.A.G.
Williams,
Triplet-triplet
energy transfer between porphyrins linked via a ruthenium(II)
bisterpyridine
complex,
Inorg. Chem., 1999, 38, 661-667.
(27) J.-P. Collin, I.M. Dixon,
J.-P. Sauvage, J.A.G. Williams,
F. Barigelletti and L. Flamigni, Synthesis
and photophysical properties of iridium(III) bisterpyridine and its
homologues:
a family of complexes with a long-lived excited state, J. Am. Chem.
Soc., 1999, 121, 5009-5016.
(26) L. Flamigni, F.
Barigelletti,
N. Armaroli, J.-P. Collin, I.M. Dixon, J.-P. Sauvage and J.A.G. Williams,
Photoinduced processes in multicomponent arrays containing transition
metal
complexes, Coord. Chem. Rev., 1999,
190-192, 671-682.
(25) A. Beeby, I.M. Clarkson,
R.S. Dickins, S. Faulkner, D. Parker, L. Royle, A.S. de Sousa, J.A.G.
Williams
and M. Woods, Non-radiative deactivation of the excited states of
europium,
terbium and ytterbium complexes by proximate energy-matched OH, NH and
CH oscillators: an improved luminescence method for establishing
solution
hydration states, J. Chem. Soc., Perkin Trans. 2, 1999, 493-504.
(24) R.S. Dickins, J.A.K.
Howard,
C.L. Maupin, J.M. Moloney, D. Parker, J.P. Riehl, G. Siligardi and
J.A.G.
Williams, Synthesis, time-resolved luminescence, NMR spectroscopy,
circular dichroism and circularly polarised luminescence studies of
enantiopure
macrocyclic lanthanide tetraamide complexes,
Chem. Eur. J., 1999, 5,
1095-1105.
(23) S. Faulkner, A. Beeby,
R.S.
Dickins, D. Parker and J.A.G. Williams, Generating a warm glow:
lanthanide
complexes which luminesce in the near-IR,
J. Fluoroescence, 1999, 9,
45-49.
(22) L.J. Govenlock, C.E.
Mathieu,
C.L. Maupin, D. Parker, J.P. Riehl, G. Siligardi and J.A.G. Williams,
Stereodifferentiation and base-pair selectivity in the binding of D and
L cationic lanthanide complexes to [(CG)6]2, [(AT)6]2
and CT-DNA, Chem. Commun., 1999, 1699-1700.
(21) T. Gunnlaugsson, D.
Parker
and J.A.G. Williams, Responsive luminescent lanthanide complexes
for
sensing pH, pO2 and hydrogencarbonate, Proc. SPIE, 1999,
3602, 186-193.
(20) S. Faulkner, D. Parker
and
J.A.G. Williams, "Parallel processing in solution", in
“Supramolecular
science: where it is and where it is going”, eds. R. Ungaro and E.
Dalcanale,
NATO-ASI, Kluwer, Dordrecht, 1999, C527, 53-67.
(19) L. Flamigni, F.
Barigelletti,
N. Armaroli, J.-P. Collin, J.-P. Sauvage and J.A.G. Williams, Photoinduced
processes in highly coupled supramolecular arrays based on a
ruthenium(II)
bisterpyridine complex and porphyrins, Chem. Eur. J., 1998, 4,
1744-1754.
(18) D. Parker and J.A.G.
Williams,
Taking
advantage of the pH and pO2 sensitivity of a macrocyclic
terbium
phenanthridinium complex,
Chem. Commun., 1998, 245-246.
(17) S. Aime, M. Botta, R.S.
Dickins,
C.L. Maupin, D. Parker, J.P. Riehl and J.A.G. Williams, Synthesis,
NMR, relaxometry and circularly polarised luminescence studies of
macrocyclic
monoamidetris(phosphinate) complexes bearing a remote chiral centre, J.
Chem. Soc., Dalton Trans., 1998, 881-892.
(16) D. Parker, P.K.
Senanayake
and J.A.G. Williams, Luminescent sensors for pH, O2,
halide
and hydroxide ions using phenanthridine as a photosensitiser in
macrocyclic
europium(III) and terbium(III) complexes,
J. Chem. Soc., Perkin Trans.
2, 1998, 2129-2134.
(15) C.L. Maupin, D. Parker,
J.A.G.
Williams and J.P. Riehl,
Circularly polarised luminescence from chiral
octadentate complexes of Yb(III) in the near-infrared, J. Am. Chem.
Soc., 1998, 120, 10563-10564.
(14) A. Beeby, R.S. Dickins,
S.
Faulkner, D. Parker and J.A.G. Williams, Luminescence from
ytterbium(III)
and its complexes in solution,
Chem. Commun., 1997, 1401-1402.
(13) D. Parker, K. Senanayake
and J.A.G. Williams, Luminescent chemosensors for pH, halide and
hydroxide
ions based on kinetically stable, macrocyclic europium
-phenanthridinium
conjugates, Chem. Commun., 1997, 1777-1778.
(12) S. Aime, A.S. Batzanov,
M.
Botta, R.S. Dickins, S. Faulkner, C.E. Foster, A. Harrison, J.A.K.
Howard,
J.M. Moloney, T.J. Norman, D. Parker, L. Royle and J.A.G. Williams, Nuclear
magnetic resonance, luminescence and structural studies of lanthanide
complexes
with octadentate macrocyclic ligands bearing benzylphosphinate groups,
J.
Chem. Soc., Dalton Trans., 1997, 3623-3636.
(11) E. Huskowska, C.L.
Maupin,
D. Parker, J.P. Riehl and J.A.G. Williams, Use of circularly
polarised
luminescence, following circularly polarised excitation, as a probe of
the chiral structure of octadentate complexes of Eu(III) and Tb(III)
with
cyclic polyazaphosphinic acid ligands,
Enantiomer, 1997, 2, 381-395.
(10) D. Parker and J.A.G.
Williams,
Perspective: Getting Excited about Lanthanide Complexation Chemistry, J.
Chem. Soc., Dalton Trans., 1996, 3613-3628.
(9) S. Aime, M. Botta, D.
Parker
and J.A.G. Williams, Extent of hydration of octadentate
lanthanide
complexes incorporating phosphinate donors: solution relaxometry and
luminescence
studies, J. Chem. Soc., Dalton Trans., 1996, 17-23.
(8) R.S. Dickins, M. Botta, D.
Parker and J.A.G. Williams,
Closely diffusing O-H, amide N-H and methylene
C-H oscillators quench the excited state of europium complexes in
solution,
Chem.
Commun., 1996, 697-698.
(7) A. Beeby, D. Parker and
J.A.G.
Williams, Photophysical studies of macrocyclic polydentate ligands
bearing naphthyl chromophores,
J. Chem. Soc., Perkin Trans. 2, 1996,
1565-1579.
(6) D. Parker and J.A.G.
Williams,
On the use of carbostyril-124 as a sensitising chromophore in
luminescent
europium and terbium complexes,
J. Chem. Soc., Perkin Trans. 2, 1996,
1581-1586.
(5) S. Aime, M. Botta, D.
Parker
and J.A.G. Williams, Nuclear magnetic resonance studies of
neutral
lanthanide(III) complexes with tetraaza-macrocyclic ligands containing
three phosphinate and one carboxamide coordinating arms, J. Chem.
Soc.,
Dalton Trans., 1995, 2259-2266.
(4) D. Parker and J.A.G.
Williams,
Luminescence behaviour of cadmium, lead, zinc, copper, nickel and
lanthanide
complexes of octadentate macrocyclic ligands bearing naphthyl
chromophores,
J.
Chem. Soc., Perkin Trans. 2, 1995, 1305-1314.
(3) S. Aime, A.S. Batsanov, M.
Botta, J.A.K. Howard, D. Parker, K. Senanayake, and J.A.G. Williams,
Solution and solid-state characterization of highly rigid,
eight-coordinate
lanthanide(III) complexes of a macrocyclic tetrabenzylphosphinate,
Inorg.
Chem., 1994, 33, 4696-4706.
(2) M. Murru, D. Parker,
J.A.G.
Williams and A. Beeby, Luminescence Behaviour of Stable Europium
and
Terbium Complexes of Tetraaza Phosphinates. Efficient
Through-Space
Energy Transfer from Phenyl to Terbium, J. Chem. Soc., Chem.
Commun.,
1993, 1116-1118.
(1) P. Mountford and J.A.G.
Williams,
Tertiary phosphine adducts of [W2(m-O2CBut)4].
Crystal structure of [W2(m-O2CBut)3(O2CBut)(PMe2Ph)2],
J.
Chem. Soc., Dalton Trans., 1993, 877-883.
Return
to J.A.G. Williams home page